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Patricks Day, come from a large Irish family

Figure 3 3.3 Characterization of MSA-DH UVvisible absorption spectroscopy of concentrated protein samples did not show the presence of a chromophoric cofactor

Enlargement of the ring system of 23 , by oxidatative cyclization of Hcy 1 /Hcy 3 side chains rather than the Hcy 1 /Cys 3 side chains of 23 resulted in a compound comprising a 14-membered macrocycle but with a somewhat lower affinity to IRAP (Ki = 5.1 nM), vide infra