Ferroptosis is known to reduce the intracellular GSH level, but the dynamics of this process remains unexplored
After the subsequent thiol exchange reaction leading to glutathionylation at Cys A and release of one GSH, a nucleophilic attack of the resolving cysteine leads to disulfide formation and the release of the (second) GS - from glutathionylated Cys A
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Moreover, the bacterial membrane itself acts as a potent immunoadjuvant, effectively heating up cold tumors and significantly improving response rates to immune checkpoint inhibitors
